Geochemistry and the optics of geospatial analysis as a preposition of water quality on a macroscale.

The water treatment depends exclusively on the identification of residues containing toxic chemical elements accumulated in NPs (nanoparticles), and ultrafine particles sourced from waste piles located at old, abandoned sulfuric acid factories containing phosphogypsum requires global attention. The general objective of this study is to quantify and analyze the hazardous chemical elements present in the leachate of waste from deactivated sulfuric acid factories, coupled in NPs and ultrafine particles, in the port region of the city of Imbituba, Santa Catarina, Brazil. Samples were collected in 2020, 2021, and 2022. Corresponding images from the Sentinel-3B OLCI satellite, taken in the same general vicinity, detected the levels of absorption coefficient of Detritus and Gelbstoff (ADG443_NN) in 443 m-1, chlorophyll-a (CHL_NN (m-3)), and total suspended matter (TSM_NN (g m-3) at 72 points on the marine coast of the port region. The results of inductively coupled plasma atomic-emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS) demonstrate that the leaching occurring in waste piles at the port area of Imbituba was the likely source of hazardous chemical elements (e.g., Mg, Sr, Nd, and Pr) in the environment. These leachates were formed due to the presence of coal pyrite and Fe-acid sulfates in said waste piles. The mobility of hazardous chemical elements potentiates changes in the marine ecosystem, in relation to ADG443_NN (m-1), CHL_NN (m-3), and TSM NN (g m-3), with values greater than 20 g m-3 found in 2021 and 2022. This indicated changes in the natural conditions of the marine ecosystem up to 30 km from the coast in the Atlantic Ocean, justifying public initiatives for water treatment on a global scale.

Nanoparticles containing hazardous elements and the spatial optics of the Sentinel-3B OLCI satellite in Amazonian rivers: a potential tool to understand environmental impacts.

The Amazon River is the longest river in the world. The Tapajós River is a tributary to the Amazon. At their junction, a marked decrease in water quality is evident from negative impacts from the constant activity of clandestine gold mining in the Tapajós River watershed. The accumulation of hazardous elements (HEs), capable of compromising environmental quality across large regions is evident in the waters of the Tapajós. Sentinel-3B OLCI (Ocean Land Color Instrument) Level-2 satellite imagery with Water Full Resolution (WFR) of 300 m was utilized to detect the highest potential for the absorption coefficient of detritus and gelbstoff in 443 m-1 (ADG443_NN), chlorophyll-a (CHL_NN) and total suspended matter concentration (TSM_NN), at 25 points in the Amazon and Tapajós rivers (in 2019 and 2021). Physical samples of riverbed sediment collected in the field at the same locations were analyzed for NPs and ultra-fine particles to verify the geospatial findings. The riverbed sediment samples collected in the field were studied by Transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM), with selected area electron diffraction (SAED), following laboratory analytical procedures. The Sentinel-3B OLCI images, based on the Neural Network (NN) were calibrated by the European Space Agency (ESA), with a standard average normalization of 0.83 µg/mg, containing a maximum error of 6.62% applied to the sampled points. The analysis of the riverbed sediment samples revealed the presence of the following hazardous elements: As, Hg, La, Ce, Th, Pb, Pd, among several others. The Amazon River has significant potential to transport ADG443_NN (55.475 m-1) and TSM_NN (70.787 gm-3) in sediments, with the possibility of negatively impacting marine biodiversity, in addition to being harmful to human health over very large regions.

Hazardous elements in urban cemeteries and possible architectural design solutions for a more sustainable environment.

The general objective of this study is to identify the presence of hazardous elements in the soils of five urban cemeteries in the city of Passo Fundo, in southern Brazil, and to design solutions (architecturally) for future cemeteries to be more sustainable by mitigating toxicological risks to the population residing in the area. A total of 250 soil samples were obtained from points within the cemeteries and in areas surrounding the two oldest cemeteries at a distance of up to 400 m. Twelve architects who design cemeteries primarily focused on sustainability were interviewed, and presented their suggestions for sustainable urban cemetery design. The Building Information Modeling (BIM) computer modeling system was utilized to present a visual representation of suggested architectural features by these architects. The concentration of Pb in the vicinity of cemeteries deserves special attention, as concentrations of this neurotoxin exceed the federal limits set by Brazil. Soil Pb values were found to exceed the limit of 72 mg kg-1 up to a distance of 400 m from the walls of cemeteries A and B, indicating the presence of a danger to human health even at greater distances. This manuscript highlights construction features that enable future burial structures to adequately mitigate the very real problem of contaminants entering the environment from current cemetery design. Two-thirds of the technicians interviewed for this manuscript, each of whom specialize in Brazilian cemetery design, highlighted the importance of revitalizing urban vegetation both when constructing and revitalizing urban vertical cemeteries.

Use of geospatial tools to predict the risk of contamination by SARS-CoV-2 in urban cemeteries.

Urban cemeteries are increasingly surrounded by areas of high residential density as urbanization continues world-wide. With increasing rates of mortality caused by the novel coronavirus, SARS-CoV-2, urban vertical cemeteries are experiencing interments at an unprecedented rate. Corpses interred in the 3rd to 5th layer of vertical urban cemeteries have the potential to contaminate large adjacent regions. The general objective of this manuscript is to analyze the reflectance of altimetry, normalized difference vegetation index (NDVI) and land surface temperature (LST) in the urban cemeteries and neighbouring areas of the City of Passo Fundo, Rio Grande do Sul, Brazil. It is assumed that the population residing in the vicinity of these cemeteries may be exposed to SARS-CoV-2 contamination through the displacement of microparticles carried by the wind as a corpse is placed in the burial niche or during the first several days of subsequent fluid and gas release through the process of decomposition. The reflectance analyses were performed utilizing Landsat 8 satellite images applied to altimetry, NDVI and LST, for hypothetical examination of possible displacement, transport and subsequent deposition of the SARS-CoV-2 virus. The results showed that two cemeteries within the city, cemeteries A and B could potentially transport SARS-CoV-2 of nanometric structure to neighboring residential areas through wind action. These two cemeteries are located at high relative altitudes in more densely populated regions of the city. The NDVI, which has been shown to control the proliferation of contaminants, proved to be insufficient in these areas, contributing to high LST values. Based on the results of this study, the formation and implementation of public policies that monitor urban cemeteries is suggested in areas that utilize vertical urban cemeteries in order to reduce the further spread of the SARS-CoV-2 virus.

Metals in the soil of urban cemeteries in Carazinho (South Brazil) in view of the increase in deaths from COVID-19: projects for cemeteries to mitigate environmental impacts.

The increasing mortality of COVID-19 can aggravate soil contamination by metals, harmful to the health of the population, requiring new projects for future cemeteries capable of mitigating these impacts to the environment, justifying the importance of studying the concentrations of metals in the soil of urban cemeteries. The paper analyzed the levels of metals in the soil of urban cemeteries in the City of Carazinho, in the state of Rio Grande do Sul, located in southern Brazil, considering the increase in deaths by COVID-19, for the purpose of future projects for cemeteries aimed at mitigating the impacts generated on the environment. The soils of the three urban cemeteries in Carazinho were sampled, with 5 internal and external points, with 3 repetitions at depths of 0-20 and 20-40 cm, adding 180 samples to measure the concentrations of Fe, Mn, Cu, Zn, Cr and Pb (g kg-1), considering the analytical sequence: (1) analysis in triplicate with mean deviation (RDS); (2) R2 of the analytical curve; (3) traceability of the pattern of each metal; (4) quantification limit of each metal (QL), with the performance of nitroperchloric digestion of the samples and the determinations of metals by flame modality atomic absorption spectrometry. Quantitative data on deaths by COVID-19 were analyzed by univariate modeling of time series, in the integrated autoregressive moving averages model. The results of this study were made available to fifteen architects, who attributed future solutions for environmentally sustainable cemeteries. The results showed high levels of copper (Cu) and iron (Fe) in the soil of the cemeteries studied. Considering the increase in deaths and subsequent burials per COVID-19 revealed a prediction for the death toll of 6,082,306 for June 9, 2022, it is assumed that metal contamination can reach even higher levels. To mitigate these levels of contamination by metals, 80% of the architect respondents expressed their preference for a vertical cemetery, with treatment of gases and effluents to mitigate environmental impacts.

Hazardous elements in the soil of urban cemeteries; constructive solutions aimed at sustainability.

Urban cemeteries on a global scale raise concerns due to their potential to concentrate differing levels of hazardous pollutants in their native soils due to the unnatural concentration of burials in a limited space. It is paramount for sustainability that designers of future cemeteries take this into account in order to minimize the deposition and movement of these contaminants within the soil profile. The objective of this manuscript is to identify the levels of certain hazardous element contamination, specifically heavy metals, in the soil of horizontal urban cemeteries that do not utilize herbicides for weed control. In this, solutions were sought for the construction of future urban cemeteries capable of mitigating further contamination of the environment by the increase in interments. The soils of three urban cemeteries (A, B and C) in the Brazilian city of Carazinho, in Rio Grande do Sul State, were sampled with 5 monitoring points in the internal area and 5 points in the external area of the cemeteries. At each point, 3 replications were performed at two depths (0-20 and 20-40 cm), totaling 180 samples in all, to determine the concentration of the following metals: copper (Cu), zinc (Zn), iron (Fe), manganese (Mn), lead (Pb), and chromium (Cr) (g kg-1). In addition, online interviews with 15 architects who design cemeteries were conducted. Architectural design solutions to mitigate environmental contamination were modeled utilizing the Building Information Modeling system (BIM). The results showed an excess of Cu in the soil of cemeteries A, B and C, surpassing the standards allowed by Brazilian federal regulations. A total of 80% of the interviewed architects expressed their preference for the vertical cemetery, with gas and effluent treatment systems to mitigate environmental impacts.

Agroforestry systems and understory harvest management: the impact on growth and productivity of dual-purpose wheat.

The objective of the study was to evaluate the growth and production efficiency of forage-grain dual-purpose wheat in two arrangements and four agroforestry systems (Intercrop-I and Intercrop-II), as well as to evaluate crop management for the wheat crops in two planting seasons (Crop Season I-2014 and Crop Season II-2015. The experiment was conducted in a randomized complete block design, factorial scheme 7x2x2, with seven cultivation systems Eucalyptus urophylla x Eucalyptus grandis Intercrop-II and Intercrop-I; Peltophorum dubium Intercrop-II and Intercrop-I; P. rigida Intercrop-I; S. parahyba Intercrop-I; a wheat monoculture with no tree species present; and two harvest management techniques (with and without harvesting of the forage species). Agroforestry systems generated shading for wheat plants, with a higher phyllochron and lower values of leaf area index of those individuals kept under trees with higher crown shading (non-deciduous trees) due to the lower transmissivity of solar radiation. The systems composed with Schizolobium parahyba in Intercrop-I and Parapiptadenia rigida in Intercrop-I provide a minor phyllochron to the wheat, resulting in a higher leaf area index and dry matter yield. Thus, the cultivation of tree species and dual-skilled agricultural crops, such as wheat, provides promising alternatives for the future use of land in tropical countries.